BMCBS - P-188 POTASSIUM DICHROMATE

Product Identification

Product ID:P-188 POTASSIUM DICHROMATE
MSDS Date:07/07/1988
FSC:6810
NIIN:00-264-6544
MSDS Number: BMCBS

Responsible Party
FISHER SCIENTIFIC, CHEMICAL DIV.
1 REAGENT LANE
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100 OR 201-796-7523

Info Phone: 201-796-7100

Cage: 1B464

Contractor
FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

Ingredients

POTASSIUM BICHROMATE (SARA III)

CAS: 7778-50-9

RTECS: HX7680000

Fraction By Weight: 100%

OSHA PEL C,0.1 MG/M3 CRO3

ACGIH TLV: 0.5 MG CR/M3; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

Hazards

LD50 LC50 Mixture:"ORAL MOUSE LD50" 190 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: NASAL ULCERATION/PERFORATION,
PULMONARY EDEMA. SKIN LESIONS, DERMATITIS. CONJUNCTIVITIS.
GASTROENTERITIS, VASCULAR COLLAPSE, LIVER DAMAGE, DIATHESIS,
NEPHRITIS, RENAL FAILURE. CHRONIC: NASAL UL CERATION, KIDNEY
DAMAGE, HEPATITIS, LUNGCANCER. DERMATITIS, SKIN ULCERATIONS.
CONJUNCTIVITIS. LIVER/KIDNEY DAMAGE.
Explanation of Carcinogenicity:HEXAVALENT CHROMIUM IS LISTED BY NTP AS
A CONFIRMED CARCINOGEN AND BY IARC AS A HUMAN CARCINOGEN.
Effects of Overexposure:EYES: REDNESS, PAIN, TEARING, BLURRED VISION,
INFLAMMATION. SKIN: IRRITATION. INHALATION: LUNG IRRITATION,
COUGHING, LABORED BREATHING, NOSE BLEEDS, WHEEZING, CHEST PAIN.
INGESTION: DIARRHEA, VERTIGO, MUSCLE CRAMPS, FEVER.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH A HISTORY OF
RESPIRATORY OR SKIN CONDITIONS MAY BE AT INCREASED RISK.

First Aid

First Aid:EYES: FLUSH WITH PLENTY OF WATER. IF IRRITATION PERSISTS, SEE
DOCTOR. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND
WATER. IF IRRITATION PERSISTS SEE DOCTOR. INHALATION: REMOVE TO
FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. SEE DOCTOR. INGESTION: DRINK
LARGE AMOUNT OF WATER, INDUCE VOMITING. SEE DOCTOR IMMEDIATELY.

Fire Fighting

Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, HALON OR DRY
CHEMICAL. FOR LARGER FIRES USE WATER SPRAY OR FOG.
Fire Fighting Procedures:MOVE CONTAINERS FROM FIRE AREA IF POSSIBLE. DO
NOT SCATTER SPILLED MATERIAL WITH HIGH PRESSURE WATER STREAMS. DIKE
FIRE CONTROL WATER FOR LATER DISPOSAL.
Unusual Fire/Explosion Hazard:WEAR PROTECTIVE EQUPMENT. DECOMPOSES
ESPECIALLY WHEN HEATED. CONTACT WITH COMBUSTIBLE MATERIALS MAY
RESULT IN IGNITION, VIOLENT COMBUSTION OR EXPLOSION.

Accidental Release

Spill Release Procedures:KEEP COMBUSTIBLES AWAY (WOOD, PAPER, OIL,
ETC.) AWAY FROM SPILLED MATERIAL. DO NOT TOUCH SPILLED MATERIAL.
WITH A CLEAN SHOVEL PLACE MATERIAL INTO A CLEAN, DRY CONTAINER AND
COVER. MOVE CONTAINERS FRO M SPILL AREA.

Handling

Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED
AREA. KEEP AWAY FROM COMBUSTIBLES. AVOID ANY PHYSICAL CONTACT. KEEP
CONTAINERS TIGHTLY CLOSED.
Other Precautions:NONE.

Exposure Controls

Respiratory Protection:USE NIOSH/MSHA-APPROVED RESPIRATOR WITH DUST
CARTRIDGE OR SUPPLIED-AIR RESPIRATOR FOR THE EXPOSURE OF CONCERN IF
TLV IS EXCEEDED.
Ventilation:LOCAL EXHAUST TO MAINTAIN EXPOSURE LEVEL BELOW TLV.
Protective Gloves:PROTECTIVE GLOVES.
Eye Protection:DUST-RESISTANT SAFETY GOGGLES.
Other Protective Equipment:USE PROTECTIVE CLOTHING AND EQUIPMENT TO
MINIMIZE SKIN CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT SHAKE
CLOTHING. REMOVE DUST BY WASHING OR VACUUMING.
Supplemental Safety and Health
NONE.

Chemical Properties

HCC:D2
Boiling Pt:B.P. Text:932F,500C
Melt/Freeze Pt:M.P/F.P Text:748F,398C
Decomp Temp:Decomp Text:932F,500C
Spec Gravity:2.68 @ 77F
pH:4.04
Solubility in Water:4.9% @ 32F
Appearance and Odor:ODORLESS, BRIGHT ORANGE-RED CRYSTALS WITH BITTER
METALLIC TASTE.

Stability

Stability Indicator/Materials to Avoid:YES
AVOID EASILY OXIDIZABLE, ORGANIC OR OTHER COMBUSTIBLE MATERIALS.
Stability Condition to Avoid:HIGH HEAT.
Hazardous Decomposition Products:TOXIC AND/OR HAZARDOUS GASES.

Disposal

Waste Disposal Methods:NOTIFY YOUR LOCAL ENVIRONMENTAL OFFICER. KEEP IN
COVERED CONTAINERS PENDING DISPOSAL. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.